Salt tectonics vs. inversion tectonics: The anticlines of the western Maestrazgo revisited (eastern Iberian Chain,Spain)     

Carlos L. Liesa  Antonio M. Casas-Sainz  Marcos Aurell  José L. Simón  Ana R. Soria 《Basin Research》2023,35(1):295-335

Many works in the last decades underline the role of evaporites, not just as a conditioning factor but as the engine for subsidence and eventually basin inversion. The western Mediterranean alpine ranges are being investigated in this regard because of the presence of discontinuous units of Permian to Triassic evaporites, deposited in the western Tethys basins. This work presents a thorough analysis of two particular structures (Cañada Vellida and Miravete anticlines) in the intraplate Maestrazgo basin (eastern Iberian Chain, Spain) in which evidence to support their reinterpretation as salt-driven structures have been recently reported. Our analysis includes (i) a comprehensive stratigraphic and structural study of the folds along their entire trace, (ii) the compilation of thickness and distribution of evaporite–bearing and supraevaporite units, paying special attention to changes in the thickness of units in relation to anticlines, and (iii) the study of fault patterns, sometimes in relation to the mechanical stratigraphy. All three aspects are also documented and discussed on a regional scale. The new data and interpretations reported here reinforce the extensional origin of the Late Jurassic–Early Cretaceous basins, and the role of regional extensional tectonics as the responsible for the development of first-order syn-sedimentary normal fault zones driving the formation and evolution of sub-basins. These basins were subsequently inverted and deformed, including the formation of complex, box-geometry anticlines that, in their turn, controlled deposition in Cenozoic basins. The review of the arguments that support the alternative of salt tectonics for the origin of such anticlines has allowed us to delve into the sedimentary and tectonic evolution of the inverted extensional basins and to propose a specific model for the development of these faulted anticlines. The role of salt levels and other interlayered detachments in the structuring of sedimentary basins and their inversion is also pondered. The observations in the eastern Iberian Chain reported here have implications to assess ongoing reinterpretations in terms of salt tectonics in other alpine basins and ranges of the western Mediterranean.  相似文献   

Geochemical comparison of waters and stream sediments close to abandoned Sb-Au and As-Au mining areas,northern Portugal     

Paula C.S. Carvalho  Ana M.R. Neiva  Maria M.V.G. Silva  Eduardo A. Ferreira da Silva 《Chemie der Erde / Geochemistry》2014

Waters from abandoned Sb-Au mining areas have higher Sb (up to 2138 μg L⁻¹), As (up to 1252 μg L⁻¹) and lower Al, Zn, Li, Ni and Co concentrations than those of waters from the As-Au mining area of Banjas, which only contain up to 64 μg L⁻¹ As. In general, Sb occurs mainly as SbO₃⁻ and As H₂AsO₄⁻. In general, waters from old Sb-Au mining areas are contaminated in Sb, As, Al, Fe, Cd, Mn, Ni and NO₂⁻, whereas those from the abandoned As-Au mining area are contaminated in Al, Fe, Mn, Ni, Cd and rarely in NO₂⁻. Waters from the latter area, immediately downstream of mine dumps are also contaminated in As. In stream sediments from Sb-Au and As-Au mining areas, Sb (up to 5488 mg kg⁻¹) and As (up to 235 mg kg⁻¹) show a similar behaviour and are mainly associated with the residual fraction. In most stream sediments, the As and Sb are not associated with the oxidizable fraction, while Fe is associated with organic matter, indicating that sulphides (mainly arsenopyrite and pyrite) and sulphosalts containing those metalloids and metal are weathered. Arsenic and Sb are mainly associated with clay minerals (chlorite and mica; vermiculite in stream sediments from old Sb-Au mining areas) and probably also with insoluble Sb phases of stream sediments. In the most contaminated stream sediments, metalloids are also associated with Fe phases (hematite and goethite, and also lepidocrocite in stream sediments from Banjas). Moreover, the most contaminated stream sediments correspond to the most contaminated waters, reflecting the limited capacity of stream sediments to retain metals and metalloids.  相似文献   

Modeling compositional compressible two-phase flow in porous media by the concept of the global pressure     

Brahim Amaziane  Mladen Jurak  Ana Žgaljić Keko 《Computational Geosciences》2014,18(3-4):297-309

We derive a new formulation for the compositional compressible two-phase flow in porous media. We consider a liquid–gas system with two components: water and hydrogen. The formulation considers gravity, capillary effects, and diffusivity of each component. The main feature of this formulation is the introduction of the global pressure variable that partially decouples the system equations. To formulate the final system, and in order to avoid primary unknowns changing between one-phase and two-phase zones, a second persistent variable is introduced: the total hydrogen mass density. The derived system is written in terms of the global pressure and the total hydrogen mass density. The system is capable of modeling the flows in both one and two-phase zones with no changes of the primary unknowns. The mathematical structure is well defined: the system consists of two nonlinear parabolic equations, the global pressure equation, and the total hydrogen mass density equation. The derived formulation is fully equivalent to the original one. Numerical simulations show ability of this new formulation to model efficiently the phase appearance and disappearance.  相似文献   

Metabolites in bile of fish from São Sebastião Channel, São Paulo, Brazil as biomarkers of exposure to petrogenic polycyclic aromatic compounds     

da Silva DA  Buzitis J  Krahn MM  Bícego MC  Pires-Vanin AM 《Marine pollution bulletin》2006,52(2):175-183

This study reports the analysis of polycyclic aromatic compound (PAC) metabolites, as biomarkers of exposure to PACs in marine environment. PAC metabolites were measured in bile samples from 14 species of demersal fish caught in the São Sebastião Channel (SSC), SE Brazilian coastline. Naphthalene (NPH) equivalents, phenanthrene (PHN) equivalents, and benzo[a]pyrene (BaP) equivalents were quantified using a reverse-phase high-performance liquid chromatography coupled with fluorescence detection method. For all samples, the means (±standard deviation, n = 37) of concentrations obtained for NPH, PHN, and BaP equivalents were, respectively, 290,000 ± 200,000 ng/g, 18,000 ± 14,000 ng/g, and 970 ± 1900 ng/g. These results indicate recent exposure of these fish to PACs in their environment. In addition, two species (Cyclichthys spinosus and Prionotus nudigula) of fish were analyzed in order to investigate local sources of PAC contamination in the SSC and the influence of the petroleum terminal in fish caught in remote areas. The results showed that these fish species potentially migrate along the channel, especially P. nudigula. Correlations among groups of PAC metabolites indicate the same petrogenic source for NPH and PHN equivalents and a combustion source (e.g., automobile, ships) for BaP equivalents. The ratio BaP/PHN equivalents (0.05 ± 0.07, n = 37) confirms the predominance of petrogenic PACs for contamination by these chemicals in this region.  相似文献   

Exploring the policy and social factors fueling the expansion and shift of sugarcane production in the Brazilian Cerrado     

Gabriel Granco  Marcellus Marques Caldas  Jason Scott Bergtold  Ana Claudia Sant’Anna 《GeoJournal》2017,82(1):63-80

Within the past decade, the sugarcane ethanol industry in Brazil has increased its production capacity to meet rising domestic demand for ethanol. However, to achieve this growth the industry has had to expand into new frontiers in the Brazilian Cerrado, specifically in the states of Goiás and Mato Grosso do Sul, which is now the second largest producing area of ethanol in Brazil. We argue that the expansion into the Brazilian Cerrado is a result of the interactions between the increase in demand, governmental policies, infrastructure, and factors that have prevented traditional sugarcane producing regions from meeting the increasing demand for ethanol. This paper analyzes the policies that have shaped the sugarcane industry in Brazil and the expansion of the industry across the country. The policies and issues examined include those that led to the concentration and consolidation of the sugarcane industry in the state of São Paulo and the consequences of this consolidation; the influence of governmental policies on the decision-making process of producers and industry; the state-level policies designed to expand the industry into Goiás and Mato Grosso do Sul states; infrastructure development; and the Sugarcane Agroecological Zoning policies. Through this study we conclude that the ethanol industry identified the Cerrado states as an opportunity for investment, given the good agricultural conditions for producing sugarcane, affordable land prices and favorable state-level fiscal incentive policies. In addition, there is a need for further regional development policies as the interaction between the sugarcane sector and regional government is likely to continue into the future.  相似文献   

Towards a spatial data infrastructure for technological disasters: an approach for the road transportation of hazardous materials     

Janaina Bezzerra Silva  Mariana A. Giannotti  Ana Paula C. Larocca  José Alberto Quintanilha 《GeoJournal》2017,82(2):293-310

Spatial data have been used for the environmental monitoring of the consequences of accidents that involve the transportation of hazardous chemical products. This spatial data infrastructure (SDI), which was created for the sharing and use of spatial data, is limited by the absence of policies to support its establishment. The main objective of this study was to explore the use of social network analysis (SNA) as a tool to identify spatial data sharing between organizations involved in the management of accidents related to road transport of hazardous materials (RTHM). In addition, to discuss the existing policies and institutional agreements, and to initiate a conceptual SDI framework for RTHM sector. In this context, the institutions that are involved with RTHM were identified and information concerning their interest in the use and sharing of spatial data via a SDI was collected through interviews and consolidated. The interviews were at 39 institutions with representative employees. The interview data were tabulated and entered into the UCINET software (2000 version) to calculate metrics of centrality. From the SNA, the flow of data among the participating institutions was identified through the visual representation of the spatial data sharing and use networks. Subsequently, the existing institutional agreements for spatial data sharing were analyzed and discussed. The compiled results enabled the proposal of a conceptual SDI framework to support the management of disasters involving RTHM, based on the application of SNA theory, and the development of a methodology that supports the analysis of interactions among the various actors of an SDI. The purpose is to facilitate the formulation of policies for the sharing of spatial data for decision-making and preventive disaster management. The results indicate that the 39 institutions share spatial data, but this sharing is not always predetermined by formal agreements. Furthermore, there is a strong demand, by the institutions involved in the management of RTHM accidents, regarding legal mechanisms governing the sharing of data for the purpose of producing maps that help to describe actions of preparedness, prevention, management and immediate relief involving RTHM incidents. Finally, it was possible to propose a conceptual framework with data that is considered essential for creating an SDI for RTHM.  相似文献   

Behaviour of a new type of Runge–Kutta methods when integrating satellite orbits     

Ana B. González  Pablo Martín  David J. López 《Celestial Mechanics and Dynamical Astronomy》1999,75(1):29-38

Recently, González, Martín and Farto have developed new numerical methods (RKGM methods) of Runge–Kutta type and fixed step size for the numerical integration of perturbed oscillators. Moreover, it seems natural to study the behaviour of these new methods for the accurate integration of orbital problems after the application of linearizing transformation, such us KS or BF due to the fact that in these variables, the structure of the problem is of the form of perturbed oscillators, for which the methods constructed are indicated. In this paper, we check the efficiency of these new methods when integrating the satellite problem. The RKGM methods show a very good behaviour when they compete with other, classical and special, methods. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Long-term phytoplankton studies in the Bahia Blanca estuary, Argentina   总被引：3，自引：0，他引：3  

Gayoso  Ana Maria 《ICES Journal of Marine Science》1998,55(4):655-660

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The impact of spatial elements on the forecasting of Spanish labour series     

Ana M. Angulo  F. Javier Trívez 《Journal of Geographical Systems》2010,12(2):155-174

In this paper, we analyse the ability of a dynamic spatial panel data model without explanatory variables to explain a variable of interest, in this case employment in the fifty Spanish provinces. The best model is a dynamic fixed effect with a spatial lag structure in an equation estimated through the unconditional ML procedure. Predictions derived from this selected model are compared with those derived from fifty seasonal ARIMA models that also treat outlier observations. The results indicate that forecasts derived from a single estimated spatial panel data model are as accurate as those derived from the estimation of fifty seasonal ARIMA models. This shows that spatial panel data models play an important role in forecasting.  相似文献   

Admissible nested covariance models over spheres cross time     

Ana?Peron  Emilio?Porcu  Xavier?EmeryEmail authorView author&#;s OrcID profile 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(11):3053-3066

Nested covariance models, defined as linear combinations of basic covariance functions, are very popular in many branches of applied statistics, and in particular in geostatistics. A notorious limit of nested models is that the constants in the linear combination are bound to be nonnegative in order to preserve positive definiteness (admissibility). This paper studies nested models on d-dimensional spheres and spheres cross time. We show the exact interval of admissibility for the constants involved in the linear combinations. In particular, we show that at least one constant can be negative. One of the implications is that one can obtain a nested model attaining negative correlations. We provide characterization theorems for arbitrary linear combinations as well as for nonconvex combinations involving two covariance functions. We illustrate our findings through several examples involving nonconvex combinations of well-known parametric families of covariance functions.  相似文献